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The Relationship Between Colloidal Stability of Atmospheric Reidues or Vacuum Residues and the Characteristics of Fractions
ZHANG Long-li, YANG Guo-hua, QUE Guo-he, et al
Abstract976)      PDF (179KB)(649)      
The colloidal stability of several residues, including Da-gang (DG), Middle East (ME), Ta-he (TH) atmospheric residues, and the corresponding vacuum residues, were measured by the mass fraction normalized conductivity. In addtion, the polar or compositional characterization of fractions of samples was performed to elucidate their effect on colloidal stability. The colloidal stability paramters of samples were from 1.45 to 8.20.   The mean molecular weight and the mean dipole moments of fractions were measured. The results show that fraction composition and the characteristics of them determined the colloidal stability of samples together and can be expressed by a formula. When the difference between dipole moment values of resins and asphaltenes is less, and the content ratio of resins to asphaltenes is bigger, the residue will be more stable. So do the heavy aromatics and asphaltenes. The ratio of saturates and light aromatics to asphaltenes is larger, the difference of polarity is larger, the sample will be more unstable.    
2010, 23 (3): 6-10. DOI: 10.3696/j.issn.1006-396X.2010.03.002
 
Reaction Conditions of Slurry-Bed Hydrocracking to Liaohe Residue
ZHANG Shu-yi, LUO hui, DENG Wen-an, LIU Dong, QUE Guo-he
Abstract269)      PDF (1614KB)(570)      
 
The Liaohe inferior residue was studied as object and the slurry-bed hydrocracking reaction to Liaohe residue was simulated by the autoclave reaction. The effects of oil-soluble dispersed Ni catalyst on residue conversion under different reaction conditions were investigated. The results show that for the oil-soluble dispersed Ni catalyst, the use of the sulfide agent is superior to without sulfide agent; sulfur is the best sulfide agent. The best reaction conditions for hydrocracking Liaohe residue using oil-soluble dispersed Ni catalyst are: oil-soluble catalyst concentration 300 μg/g, the initial hydrogen pressure of 7.0 MPa, reaction temperature is standard temperature (t+5 )℃, reaction time of 1 h.
2008, 21 (3): 57-59.
Suspension Bed Hydrocracking of Atmospheric Residue From Dagang Oil Field
ZHANG Lei,MU Bao-quan, DENG Wen-an, QUE Guo-he
Abstract350)      PDF (849KB)(305)      
 
Suspension bed hydrocracking technology and water soluble catalyst were used for upgrading of atmospheric residue from Dagang oil field. The relations among metal composition of the catalyst, reaction conditions, coke forming and conversion were systematically investigated. After optimization, the yields of AGO and VGO are 21.2% and 47.7% respectively from processing atmospheric residue under the condition of 430 ℃, 1.0 h-1 space velocity, 7 MPa and catalyst addition amount with 300 μg/g in once through operation, toluene insolubles yield level of 1.4%, a total conversion of AR which has a boiling point lower than 524 ℃ can reach above 80%.The constitutes of catalyst and reaction temperature are the main factors which affect the conversion of materials and coke formation, the conversion of materials and coke formation increase with the extend of reaction time, the conversion has little change and the trend of coke formation decreases with the increase of reaction pressure. The recycling can improve the conversion of residue but the degree is too small.
2007, 20 (1): 52-55.